Does anyone know of a car service that will pick up at home to work in the morning and then work to home in the evening from Monday to Friday?

where do u live and work?

Just book a taxi to be at your place in the morning and at your work place in the evening at a certain time every day. Some taxi firms have no booking fee but others do so you'll have to select the right firm. Get a Chinese friend to organise this for you.

Taxi companies will not accept booking during peak morning and evening office hours.

Thats interesting, I booked one this morning to pick me up at my place at 7.45 and he was waiting.

^ did u have a distant destination (e.g. airport)?

But not from 8 am to 9 am.
Tried to book one last night and all of them said fully booked.

There are several threads that address this question.

My wife was unable to book a long-term deal to get to/from work with the local cab companies, at least during peak hours. Instead, she found a cab driver she liked and made a private arrangement. For an extra RMB 10 each way (RMB 15 on rainy days), the driver takes my wife to work and brings her home. So far, so good.

emerson wrote:There are several threads that address this question.

My wife was unable to book a long-term deal to get to/from work with the local cab companies, at least during peak hours. Instead, she found a cab driver she liked and made a private arrangement. For an extra RMB 10 each way (RMB 15 on rainy days), the driver takes my wife to work and brings her home. So far, so good.

Seems like a sensible solution.

I have a friend that has used the same cab driver for over a year. He waits to pick her up in the morning and picks her up at night.

She pays him the cab fair, 30-40 rmb a day, and no additional charge.

Dazhong taxis take my daughter to school every morning at 8. There is an extra charge for the booking but it is only 4 rmb.